| 尹国川,奚祖威.钌配合物Ru（PA）2Cl对C—H键的选择氧化研究[J].分子催化,1999,(2):93-98 |
| 钌配合物Ru（PA）2Cl对C—H键的选择氧化研究 |
| Study on the Phase Transfer Catalytic Reduction of Deuterated Acetophone\|d8 |
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| DOI： |
| 中文关键词: 钌配合物 C－H键 选择氧化 碳氢键 氧化 催经剂 |
| 英文关键词:Deuterated acetophenone\|d8, Phase transfer catalytic reduction, Ni\|Al alloy, Deuterated 1\|phenylethanol\|d10 |
| 基金项目:国家高技术863－416－3资助项目 |
| 尹国川 奚祖威 |
| 中国科学院大连化学物理研究所 |
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| 中文摘要: |
| 合成了一种新的钌配合物Ｒｕ（ＰＡ）２Ｃｌ，以叔丁基氢化过氧化物为氧源，考察了它对甲苯，乙苯和环己烷的催化氧化反应。发现它对环己烷和乙苯有良好的催化活性。在适当的反应条件下，催化环己烷氧化成环己醇和环己酮，基于产物的催化转化数达１０２１。 |
| 英文摘要: |
| Deuterated acetophenone\|d8(C6D5\|COCD3) was reduced by nickel\|aluminum (Ni\|Al) alloy in NaOD\|D2O solution to give deuterated 1\|phenylethanol\|d10(C6D5\|CDODCD3) in the preseence of phase transfer catalysts (PTC). The reduction procedure was described, and the mechanisms of the phase transfer reduction were proposed. It is found that when 2.5%10% mole ratio of the PTC such as polyethylene glycol (PEG300 or 400), \|cyclodextrin ( \|CD) and dibenzo\|18\|crown\|6 (DB18C6),is used, the yield of C6D5\|CDODCD3 can be increased to more than 90%. |
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