李越湘,徐玉欣,彭绍琴.空心玻璃微球负载TiO2光催化回收银[J].分子催化,2003,(5):376-379
空心玻璃微球负载TiO2光催化回收银
Immobilization of TiO2 on Hollow Glass Microbeads and Photocatalytic Recovery of Silver
  修订日期:2003-02-10
DOI:
中文关键词:  光催化 TiO2 负载化 空心玻璃微球 银 超声波
英文关键词:Photocatalysis,Immobilization of TiO_2,Hollow Glass Microbead,Silver,Ultrasonic
基金项目:江西省自然科学基金,南昌大学校科研和教改项目,0120007,,,
李越湘  徐玉欣  彭绍琴
南昌大学,化学与材料学院化学系,江西,南昌,330047
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中文摘要:
      以钛酸四丁酯的溶胶为前驱体,通过浸渍法制备漂浮型光催化剂.它的光催化活性比P25高,且易于分离回收.沉积在催化剂上的金属银可通过超声震荡有效回收,该操作简单,具有实际应用前景.循环使用3次的光催化剂的催化活性未显著降低;但第4次由于催化剂负载TiO2损失量大,活性明显降低.讨论了反应机理.
英文摘要:
      The floating photocatalyst TiO\-2 on glass microbeads was prepared by impregnating the beads with the sol from precursor tetra\|n\|butyl titanate. It has higher activity than P25 TiO\-2 and can be separated easily. Silver is efficiently recovered from the catalyst by ultrasonic, which is a convenient and promising method for application. The activity does not decrease markedly after the catalyst was recycled for three times; but it decrease quickly for the fourth time because loss of loaded TiO\-2 on the beads is too much. The reaction mechanism was discussed.
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