| 黄汉民.手性环状二胺催化的不对称Diels-Alder反应[J].分子催化,2011,(1):6-10 |
| 手性环状二胺催化的不对称Diels-Alder反应 |
| Asymmetric Diels-Alder reaction catalyzed by chiral diamines |
| 投稿时间：2010-10-23 修订日期：2010-12-30 |
| DOI： |
| 中文关键词: 手性二胺，布朗斯特酸，Diels-Alder反应,不对称催化 |
| 英文关键词:Chiral diamine, Br鴑sted acid, Diels-Alder reaction, Asymmetric catalysis |
| 基金项目: |
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| 摘要点击次数: 1033 |
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| 中文摘要: |
| 研究了一种结构新颖、合成路线简单的手性二胺催化的Diels-Alder反应，考察了各种Brønsted酸助催化剂、温度、溶剂和手性二胺分子中上不同的取代基对反应的影响。研究结果表明：该类催化剂在催化Diels-Alder反应中表现出较高的催化活性和中等的立体选择性。 |
| 英文摘要: |
| A series of chiral diamines with novel rigid structure have been successfully applied in the Diels-Alder reaction. The effect of reaction conditions such as Brønsted acid, temperature, solvent and different substitutes on the diamines was also extensively investigated. The results showed that the Diels-Alder reaction processed smoothly with high yield and moderate enantiomeric excess under the optimized reaction conditions. |
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