| 黄汉民,胡金金,左秀锦.Grubbs催化剂合成研究进展[J].分子催化,2012,(6):566-575 |
| Grubbs催化剂合成研究进展 |
| Progress in the Synthesis of the Grubbs Catalysts |
| 投稿时间：2012-10-27 修订日期：2012-11-23 |
| DOI： |
| 中文关键词: 烯烃复分解反应 Grubbs催化剂 合成 |
| 英文关键词:Olefin metathesis, Grubbs catalyst, Synthesis |
| 基金项目:国家自然科学基金项目（面上项目21172226，重点项目21133011） |
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| 中文摘要: |
| 烯烃复分解反应是构建碳碳双键的有效方法，在有机合成及高分子材料合成中得到广泛应用，开发催化烯烃复分解反应的新型、高效催化剂已成为该领域研究的重点。其中，Grubbs催化剂由于具有反应活性高，所需反应条件温和，对空气、水和大量官能团耐受性好的优点，在烯烃复分解反应中的应用越来越广泛，受到了国内外研究人员的重视。本文综述了Grubbs催化剂的发展过程及其合成方法，并且分析了不同合成方法的优缺点及该类催化剂仍然存在的问题。 |
| 英文摘要: |
| As an effective method for the formation of C-C double bond, olefin metathesis has been widely used in the organic and polymer chemistry. The development of new and efficient catalysts for this reaction has become to be the key point to the utility of this reaction. In particular, because of the high reactivity, mild reaction condition, remarkable tolerance toward oxygen, water and functional groups, the Grubbs catalyst has been used extensively in the olefin metathesis reaction and attracts the attention of more and more chemists. Herein, we introduce the development and the synthesis method of Grubbs catalysts. Besides, the advantage and disadvantage of different synthesis methods as well as the problem of Grubbs catalysts were also analyzed in this paper. |
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