杨俞,夏龙飞,范泽云,陈威,陈小平,袁坚,上官文峰.纳米Cu的高分散制备及其对Cu/TiO2光催化分解水制氢性能的影响[J].分子催化编辑部,2014,(2):182-187
纳米Cu的高分散制备及其对Cu/TiO2光催化分解水制氢性能的影响
Preparation of Nano Copper with High Dispersion and Its Effects on Photocatalytic Hydrogen Production on Cu/TiO2
投稿时间:2014-01-13  修订日期:2014-01-27
DOI:
中文关键词:  氢能、光催化、Cu/P25、高分散
英文关键词:Hydrogen energy, photocatalysis, Cu/P25, high dispersion
基金项目:国家高技术研究发展计划(863计划),上海市国际合作项目
作者单位E-mail
杨俞 上海交通大学 yy3431@gmail.com 
夏龙飞 上海交通大学 xialongfei0102@163.com 
范泽云 上海交通大学 fzy0219@gmail.com 
陈威 上海交通大学 chanwee@163.com 
陈小平 上海交通大学 chenxiaoping880411@126.com 
袁坚 上海交通大学 janeyuan@sjtu.edu.cn 
上官文峰 上海交通大学 shangguan@sjtu.edu.cn 
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中文摘要:
      本文利用光沉积法及浸渍法在P25上负载了纳米Cu颗粒,通过XRD、TEM、BET、TPx等手段对Cu在TiO2上的负载状态进行表征,并考察了光催化分解水制氢活性。结果表明:光沉积法比浸渍法负载的Cu具有更好的分散性,组成不同的Cu源的阴离子会导致负载在TiO2表面的Cu分散度不同并影响其光催化活性。以Cu(OAc)2为Cu源通过光沉积法制备的Cu/P25光催化活性最好,其中2 wt% Cu/P25的产氢速率为782.2 μmol/h,接近于Pt/P25的活性。
英文摘要:
      Copper nanoparticles was loaded on the P25 by impregnation mothed and photodeposition mothed, respectively. The prepared samples were characterized by XRD, TEM, BET and TPx, and their activity was evaluated by photocatalytic hydrogen evolution from water splitting. Compared to impregnation mothed, the photodeposition mothed gave rise to high dispersion and uniformity of Cu nanoparticles on the surface of P25, and the photocatalytic activity and the dispersion were affected by different copper sources. It was found that Cu/P25 prepared with Cu(OAc)2 by photodeposition had excellent photocatalytic activity, and the rate of hydrogen evolution on 2 wt% Cu/P25 was 782.2 μmol/h, being approaching to the activity of Pt/P25.
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