| 张占金.腙为配体的高效铜催化的胺的N-芳基化反应[J].分子催化,2016,30(5):420-427 |
| 腙为配体的高效铜催化的胺的N-芳基化反应 |
| Highly Efficient Copper-Catalyzed N-Arylation of Amine with Arylhalide Using Hydrazone as Ligand |
| 投稿时间：2016-06-27 修订日期：2016-09-25 |
| DOI： |
| 中文关键词: 胺 芳卤 腙 N-芳基化 |
| 英文关键词:amine aryl halide hydrazone N-arylation |
| 基金项目: |
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| 摘要点击次数: 1159 |
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| 中文摘要: |
| 发展了一种温和、高效的以腙为配体的铜催化系统，该系统用于催化胺与芳卤的N-芳基化反应。反应在相对温和的条件下进行，并得到了良好的分离收率。腙配体是稳定的、价廉的，并易于通过简单的方法，从市场可得的原料制备。 |
| 英文摘要: |
| A mild and highly efficient copper-catalyzed system for N-arylation of amines with aryl halides using hydrazone as ligand was developed.The reactions were carried out under relative mild condition and good yields were obtained. The hydrazone ligands are stable, low-coste and easily prepared from inexpensive, commercially available starting materials using a simple, efficient method. |
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