| 江淑萍,叶兴凯,吴越.细胞色素P－450单加氧酶的模拟──轴向配体在锰卟啉／亚碘酰苯催化环己烷加氧反应中的作用[J].分子催化,1996,(1): |
| 细胞色素P－450单加氧酶的模拟──轴向配体在锰卟啉／亚碘酰苯催化环己烷加氧反应中的作用 |
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| DOI： |
| 中文关键词: 环己烷，锰卟啉，轴向配体，氧化，单加氧酶 |
| 英文关键词:Cyclohexane,Manganese porphyrin,Axial ligand,Oxygenation,Monooxygenase |
| 基金项目:国家自然科学基金 |
| 江淑萍 叶兴凯 吴越 |
| 中国科学院长春应用化学研究所 |
| 摘要点击次数: 1404 |
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| 中文摘要: |
| 细胞色素Ｐ－４５０单加氧酶的模拟──轴向配体在锰卟啉／亚碘酰苯催化环己烷加氧反应中的作用江淑萍，叶兴凯，吴越（中国科学院长春应用化学研究所，长春１３００２２）关键词环己烷，锰卟啉，轴向配体，氧化，单加氧酶目前，细胞色素Ｐ－４５０单加氧酶的模拟有两个途... |
| 英文摘要: |
| A series of manganese porphyrin complexes containing alkali ligands was synthesized,and the catalytic activity as well as the physico-chemical properties of these complexes were examined and compared with those of the catalyst systems containing MnTPPCl and ligands added before the reaction.Based on the experimental results,conclusion is drawn that the catalytic activity of oxidation of the fomer was higher than that of the latter,and that their catalytic activity was related to the electron-donating ability of the ligands. |
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