程谟杰,杨亚书.ZnHZSM-5上脱氢环化芳构化过程的探讨[J].分子催化,1996,(6):
ZnHZSM-5上脱氢环化芳构化过程的探讨
Study on Dehydrocyclization and Aromatization Process over ZnHZSM 5 Catalyst
  
DOI:
中文关键词:  ZnHZSM-5,己烷,己烯,甲基环戊烷,脱氢环化,芳构化
英文关键词:ZnHZSM 5, Hexane, Hexene, Methylcyclopentane, Dehydrocyclization, Aromatization
基金项目:
程谟杰  杨亚书
中国科学院大连化学物理研究所催化基础国家重点实验室
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中文摘要:
      以正己烷、环己烷、甲基环戊烷、1-己烯和环己烯等分子探针反应,考察了单B酸型HZSM-5、Zn-L酸型ZnNaZSM-5和双中心型ZnHZSM-5(B酸和Zn-L酸)催化剂的性能,探讨了B酸中心和Zn-L酸中心在芳构化过程中的作用.实验结果表明,B酸中心有利于环化,L酸中心有利于脱氢芳构化.单具B酸或Zn-L酸中心催化剂上,直链烃分子的芳构化性能较差,当两种中心同时存在时,双功能互相促进,加快芳构化过程.文中还对C6分子脱氢环化芳构化过程进行了讨论
英文摘要:
      The catalytic behavior of single Brnsted acid center model catalyst HZSM 5, single zinc Lewis acid center model catalyst ZnNaZSM 5 and double center model catalyst ZnHZSM 5 have been investigated using n hexane,cyclohexane,methylcyclohexane,1 hexene and cyclohexene respectively, and the different roles of Brnsted acid centers and zinc Lewis acid centers in aromatization have been discussed. Brnsted acid centers promote the cyclization of alkene and zinc Lewis acid centers promote the dehydrogenation of alkanes and alkenes. The aromatization of aliphatic alkanes or alkenes on the catalysts solely with Brnsted acid centers or zinc Lewis acid centers shows a low conversion and a low selectivity to aromatics. When both Brnsted acid centers and zinc Lewis acid centers are present in the same catalyst, the cyclization and the dehydrogenation promotes each other to achieve a high rate of aromatization. The different aromatization paths of different C 6 molecules have also been discussed.
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