| 刘湘,李纪国.金鸡纳生物碱的金属络合物用于苯乙酮的不对称催化还原[J].分子催化,1997,(4):305-308 |
| 金鸡纳生物碱的金属络合物用于苯乙酮的不对称催化还原 |
| Catalytic Asymmetric Reduction of Acetophenone in the Presence of Some Metal Complexes of Cinchona Alkaloids |
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| DOI： |
| 中文关键词: 金鸡纳生物碱 还原 苯乙酮 金属配合物 催化 |
| 英文关键词:Cinchona alkaloid, Chiral complex, Asymmetric reduction, Acetophenone, |
| 基金项目: |
| 刘湘 李纪国 |
| 无锡轻工大学化工系，南京大学化学系 |
| 摘要点击次数: 981 |
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| 中文摘要: |
| 金鸡纳生物碱的金属络合物用于苯乙酮的不对称催化还原刘湘（无锡轻工大学化工系无锡２１４０３６）李纪国张正（南京大学化学系南京２１００９３）关键词金鸡纳生物碱手性络合物不对称还原苯乙酮分类号Ｏ６４３．３２近１０多年来，前手性酮的不对称还原反应作为制备光学... |
| 英文摘要: |
| Chiral complexes prepared in situ from cinchona alkaloids and metal salts were applied to the catalytic asymmetric reduction of acetophenone for the first time. The results of using chiral complexes were much better than that of using chiral ligands. Effect of chiral complexes prepared from chiral ligands and various metal salts and effect of different catalyst compositions on reaction were also examined. The highest ee value of 1 phenylethanol was 61% under suitable reaction conditions. |
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