| 葛少辉,张明慧,李伟,牟诗诚,陶克毅.酸处理再生NiB非晶态合金催化剂[J].分子催化,2006,(4):363-365 |
| 酸处理再生NiB非晶态合金催化剂 |
| Regeneration of Amorphous NiB Alloy by Acid Treatment |
| 投稿时间：2005-09-07 |
| DOI： |
| 中文关键词: NiB非晶态合金,环丁烯砜加氢,酸处理 |
| 英文关键词:Amorphous alloy,NiB,Sulfolene hydrogenation,Acid treatment, |
| 基金项目:天津市自然科学基金 |
| 葛少辉 张明慧 李伟 牟诗诚 陶克毅 |
南开大学化学学院新催化材料科学研究所 天津300071(葛少辉，张明慧，李伟，陶克毅)
，国家纳米技术产业化基地 天津300457(牟诗诚)
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| 中文摘要: |
| 近年来,非晶态合金由于在催化加氢反应中表现出优良的催化活性和选择性而受到广泛关注[1,2].其中,化学还原法制备的超细N iB非晶态合金具有很高的催化活性,但该类催化剂易于晶化和氧化失活,限制了其工业应用[3,4].因此,提高N iB非晶态合金的稳定性和抗氧化性引起广泛关注.目前, |
| 英文摘要: |
| The amorphous NiB alloy was prepared by chemical reduction and used in the hydrogenation of sulfolene to sulfolane.The used catalyst was treated by acid at different conditions.The catalyst was characterized by ICP, XRD,TEM and SAED.The results shows that the oxide in the deactivated amorphous NiB alloy decreases obviously after the treating with acid(pH=2).The regenerated catalyst exhibits excellent catalytic activity and the amorphous structure is preserved. |
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