| 王丽苹.羧基配体金属有机骨架材料作为催化剂的研究进展[J].分子催化,2015,(3):275-287 |
| 羧基配体金属有机骨架材料作为催化剂的研究进展 |
| Progress in metal-organic frameworks based on the carboxyl ligands as the catalyst |
| 投稿时间：2015-04-22 修订日期：2015-06-05 |
| DOI： |
| 中文关键词: 金属有机骨架材料 催化剂 反应 应用 |
| 英文关键词:metal-organic framework catalyst reaction application |
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| 中文摘要: |
| 金属有机骨架材料（Metal-organic frameworks, MOFs）是由金属离子与含N、O等多齿有机配体自组装形成的一类新型多孔材料。MOFs具有孔道结构规整，孔尺寸具有可调控性、比表面积大，催化活性位丰富多彩和热稳定性好等特点，因此MOFs在催化领域的应用受到人们的普遍关注。本文综述了MOFs作为催化材料的一些特点，对其在催化加氢、CO氧化反应、Knoevenagel反应、偶联反应、酯交换反应、不对称催化等反应中的应用进行了评述。 |
| 英文摘要: |
| Metal-organic frameworks (MOFs) are a new class of crystalline porous materials composed of metal ions and multidenante organic ligands containing O and/or N atoms by self-assembling. Due to their well-defined pore structure, cavity sizes controllable by selecting and assembling metal ions and organic ligands, larger specific surface area, richer catalytic sites and good thermal stability, the application of MOFs in catalysis has attracted considerable attention. In this work, the properties of metal-organic frameworks as catalysts are reviewed, and the application of metal-organic frameworks based on the carboxyl ligands in hydrogenation, CO oxidation, Knoevenagel condensation reaction, coupling reaction, transesterification and asymmetric catalysis are summarized. |
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