| 汪兵洋,郑治文,赵康,杨磊,刘建华,夏春谷.非共价键功能化石墨烯/碳纳米管负载型金属配合物催化剂及催化反应中的应用[J].分子催化,2019,33(1):90-101 |
| 非共价键功能化石墨烯/碳纳米管负载型金属配合物催化剂及催化反应中的应用 |
| Application of Non-covalent Functionalized Graphene/Carbon Nanotubes Supported Metal Complex Catalyst in Catalytic Reaction |
| 投稿时间：2018-01-15 修订日期：2018-01-29 |
| DOI： |
| 中文关键词: 石墨烯 碳纳米管 金属配合物 非共价键 催化 |
| 英文关键词:graphene carbon nanotubes metal complexes non-covalent bonds catalysis |
| 基金项目:国家自然科学基金项目（No.21673260；21373248），中国科学院"西部之光"—"西部青年学者"项目A类 |
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| 摘要点击次数: 1593 |
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| 中文摘要: |
| 碳材料（石墨烯、碳纳米管）具有超大的比表面积、高机械强度、化学稳定性、环境友好等特点，使得其作为一类新型非均相催化剂的优良载体，固载的金属配合物催化剂在许多催化反应中得到了广泛的应用.由于弱相互作用（π-π键、氢键、静电）功能化可以有效的保护碳材料的完整性，从而更好地发挥碳材料本身的优异性能.通过改变温度、溶液极性、外场力来调控非共价键功能化碳材料催化剂在催化反应中载体与催化剂的吸附与分离，使其具有均相催化剂优良的催化活性和多相催化剂的可回收性.综述了近些年来非共价键功能化石墨烯和碳纳米管固载的金属配合物催化剂在催化反应中的研究进展. |
| 英文摘要: |
| Carbon materials (graphene and carbon nanotubes) are characterized by large specific surface area, high mechanical strength, chemical stability and environmental friendliness, which make them excellent supports for a new type of heterogeneous catalysts. The supported metal complexes catalysts have been widely used in many catalytic reactions. the functionalization of weak interaction (π-π interaction, hydrogen interaction, electrostatic interaction) can effectively protect the integrity of carbon materials, so as to better play the excellent performance of carbon materials themselves. By changing temperature, solution polarity and external field force, the adsorption and separation of support and catalyst of non-covalent functionalized carbon material catalyst in catalytic reaction can be regulated, so that it has excellent catalytic activity of homogeneous catalyst and recyclability of heterogeneous catalyst. Recent advances in non-covalent functionalized graphene and carbon nanotubes supported metal complex catalysts for catalytic reactions were reviewed. |
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